目  录
1  绪 
论···························································································································· 1
1.1  应用化学专业实验的教学目的和要求··············································································· 1
1.2  实验室注意事项和安全条例···························································································· 1
1.3  实验室三废处理规范······································································································ 8
1.4  事故的处理和急救········································································································· 9
1.5  应用化学专业实验的学习方法······················································································· 11
1.6  实验报告的撰写·········································································································· 12
2  现代分析技术实验·········································································································· 13
实验2.1  紫外-可见分光光度法测定饮料中的苯甲酸钠含量····················································· 13
实验2.2  苯甲酸红外光谱的测定及谱图解析——KBr晶体压片法制样······································ 16
实验2.3  饮料中苯甲酸和山梨酸含量的气相色谱法测定························································· 19
实验2.4  X射线衍射法测聚合物的分子量分布······································································ 23
实验2.5  差示扫描量热法测定聚合物的热物性······································································ 27
实验2.6  生物样品中微量元素Zn，Ca，Mg，Fe含量测定····················································· 32
实验2.7  中成药样品中砷含量测定——原子荧光法······························································· 37
实验2.8  线性扫描伏安法测定维生素C的含量····································································· 40
实验2.9  分子荧光法测定维生素B2的含量·········································································· 44
实验2.10  间接原子吸收光谱法测定生物样品中碘含量·························································· 46
实验2.11  槲皮素和血清蛋白的相互作用·············································································· 47
实验2.12  中空纤维膜液相微萃取——液相色谱法检测痕量塑化剂·········································· 48
实验2.13  工业废水中有机污染物的分离与鉴定···································································· 50
3  有机合成实验················································································································ 52
实验3.1  ?-萘乙醚（?-ethoxynaphthalene）····································································· 52
实验3.2  乙酰水杨酸（Acetylsalicylic acid）········································································· 55
实验3.3  ?-己内酰胺（?-caprolactam）··········································································· 59
实验3.4  2-甲基-2-己醇（2-Methyl-2-hexanol）····································································· 63
实验3.5  香豆素-3-羧酸（Coumarin-3-carboxylic acid）························································· 67
实验3.6  内型-降冰片-顺-5,?6-二羧酸酐（endo-norbornene-cis-5,?6-dicarboxylic
anhydride）· 71
实验3.7  S?-?-苯乙胺（L-1-Phenylethylamine）································································ 75
实验3.8
??（E）-1,?2-二苯乙烯（Trans-Stilbene）·························································· 80
实验3.9  苯妥英钠（Phenytoin sodium）·············································································· 84
实验3.10  二茂铁（Ferrocene）··························································································· 88
实验3.11  离子液体bmimBF4（Butyl-3-methylimidazolium
tetrafluoroborate）························ 91
实验3.12  微波辐射法合成肉桂酸（Cinnamic acid）····························································· 94
4  精细化学品实验············································································································· 97
实验4.1  肥皂的制备·········································································································· 97
实验4.2  从植物中提取精油······························································································ 100
实验4.3  食品赋形剂——果胶的制备················································································· 102
实验4.4  羧甲基淀粉胶黏剂的制备···················································································· 104
实验4.5  防晒霜的配制····································································································· 106
实验4.6  由纤维素类生物质制燃料乙醇·············································································· 108
实验4.7  阴离子表面活性剂——十二烷基苯磺酸钠的制备···················································· 110
实验4.8  超细轻质碳酸钙的制备························································································ 112
实验4.9  洗发香波的制备································································································· 115
实验4.10  绿色能源——生物柴油的制备············································································ 118
5  高分子化学实验··········································································································· 121
实验5.1  苯乙烯自由基悬浮聚合························································································ 121
实验5.2  醋酸乙烯酯溶液聚合··························································································· 123
实验5.3  醋酸乙烯酯乳液聚合··························································································· 127
实验5.4  丙烯酰胺水溶液聚合··························································································· 130
实验5.5  酸催化酚醛树脂的合成························································································ 132
实验5.6  界面聚合法制备尼龙610····················································································· 135
实验5.7  苯乙烯与马来酸酐的交替共聚合及产物的FTIR测定·············································· 139
实验5.8  无皂乳液聚合法合成单分散高分子胶体微球·························································· 141
实验5.9  甲基丙烯酸甲酯聚合物综合实验··········································································· 144
实验1  甲基丙烯酸甲酯的精制·························································································· 144
实验2  甲基丙烯酸甲酯本体聚合及成型············································································· 145
实验3  黏度法测定PMMA溶液的分子量··········································································· 147
实验4  差示扫描量热仪测PMMA的玻璃化转变温度··························································· 151
实验5.10  苯乙烯阳离子聚合综合实验··············································································· 159
实验1  苯乙烯的精制······································································································· 159
实验2  苯乙烯阳离子聚合································································································· 160
实验3  GPC测聚苯乙烯的分子量分布················································································ 161
实验5.11  丙烯酸酯乳液的制备及性能表征········································································· 164
实验5.12  吸附食品油烟多孔丙烯酸酯树脂的合成及表征····················································· 166
参考文献·························································································································· 168